Series
Season 2
In "Magic Bonding," Livy comes to Alfea to ask for help, as the Pixies' friend, Aisha, had not returned after she went out to save some captured pixies.
In "The Mysterious Stone," she performs a puppet show for the Pixie Pets.
In "Pixie Village", she plays an important part as she is sent to Pixie Village to find an antidote for the poisoned Professor Avalon. She unknowingly ends up leading Icy to the Pixie Village; Icy begins destroying it, forcing the Village's Codex Guardian to give up the Codex. Before Icy can take the Codex, Livy makes an attempt to stop her by surfing on it. Icy ends up chasing Livy into Downland where they encounter Princess Amentia. Livy explains the situation, and lets Amentia take the Codex from her. Icy and Amentia start fighting, and eventually Darcy and Stormy show up and help Icy defeat her and take the Codex.
Season 3
Livy appeared in an episode when she delivered a letter to the pixies.
Season 4
Livy appears briefly in the Season 4.
Season 6
Movies
The Secret of the Lost Kingdom
Along with the other pixies, she appears in the first movie. She helps in healing Alfea and its students. She also plays with Bloom while everyone is in the tree.